The gradient color used for emphasizing the upper portion of the glossy effect when the control is in mouse over state.
Below the button with its default value on the left and with the VistaColorGlossyEmphUpper property set to yellow on the right (in order to enhance the effect the opacity value of the VistaOpacityGlossyEmphUpper property has been raised respect to its default):
 
The gradient effect of this color can be enhanced/reduced through the VistaOpacityGlossyEmphUpper property.
For further details about settings for the Vista's Aero style, see the How to manage colors of Vista's Aero style tutorial.
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